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Organic Conductive Materials

Organic Semiconductive Polymer: Verazol® HT Series (P3HT)
Feature 2: Photovoltaic Performance

By varying molecular weight of P3HT, the nanophase separation structure in the bulk heterojunction can be adjusted. This advantage is expected to allow control of OPV properties such as Jsc (short-circuit current) and Voc (open-circuit voltage).

Photovoltaic Performance

P-type and n-type semiconductors are required to fabricate organic photovoltaics. P3HT is used for the p-type and fullerene is used for the n-type. Organic photovoltaics are produced by dissolving a mixture of these two types of organic semiconductors, coating the solution onto a base plate attached with electrodes to make a thin film, and finally, forming electrodes on the organic thin film. Since the fabrication process is so simple, organic photovoltaics are expected to become the next-generation solar cells.

Surface AFM of bulk heterojunction layer (P3HT/PCBM = 1:1)

The yellow areas in the above photos are P3HT and the black areas are fullerene (PCBM). As shown, a finer nanophase separation structure has been achieved by using higher molecular weight polymerization techniques.

Cell structure: ITO glass/PEDOT: PSS/P3HT:PCBM/LiF/Al, Cell area: 4 mm2

P3HT Brend ratio
(P3HT:PCBM)
(mg/ml)
RMS
(nm)
Jsc
(mA・cm2)
Voc
(V)
F.F. Eff
(%)
Company A's product (equivalent to HT-005)
Verazol® HT-005
Verazol® HT-030
20 : 20
20 : 20
9 : 9
9.03
16.5
4.47
10.3
11.1
11.4
0.59
0.54
0.55
0.60
0.64
0.61
3.6
3.8
3,8
Polymer Journal, 2013, 454, 129.

・Performance is equivalent to competing products.
・The ultra-high molecular weight grade can reduce the amount of semiconductors, leading to cost savings.
・The ultra-high molecular weight grade provides a high level of smoothness.

Feature 3: Excellent Processability
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